Priprava policikličkih sustava fotokemijskom reakcijom u kiselom mediju

undergraduate thesis

• Title (english): Synthesis of polycyclic structures via photochemical reaction in acidic medium
• Author: Kristina Bukač
• Mentor: Dragana Vuk (mentor)
• Committee member: Dragana Vuk (predsjednik povjerenstva)
• Committee member: Ivana Šagud (član povjerenstva)
• Committee member: Mirta Čizmić (član povjerenstva)
• Granter: University of Zagreb; Faculty of Chemical Engineering and Technology; Zagreb
• Defense date and country: 2017-09-15, Croatia
• Scientific / art field, discipline and subdiscipline: NATURAL SCIENCES; Chemistry; Organic Chemistry

Abstract

Početni spoj β,β´-disupstutuirani 3-furanski derivat o-divinilbenzen 1 sintetiziran je Wittigovom reakcijom. Produkt je dobiven kao smjesa cis,cis-, cis,trans-, i trans,trans- izomera. Izomeri su izolirani i spektroskopski potpuno okarakterizirani. U svrhu proučavanja utjecaja heteroatoma na strukturu dobivenog produkta provedena je fotokemijska reakcija spoja 1 u kiselom mediju. Tom reakcijom dobiven je novi spoj 2 koji je izoliran i u potpunosti spektroskopski okarakteriziran.

Abstract (english)

Starting 3-furyl-derivative o-divinylbenzene has been synthesized by Wittig reaction as mixture is made of cis,cis-, cis,trans- i trans,trans- isomers which has been isolated and spectroscopically characterised. In aim to investigate the influence of photochemical reaction, compound 1 was irradiated in acidic medium. The polycyclic derivate 2 was isolated as main product, and it was spectroscopically characterised.

• Keywords: heterociklički spojevi; furan; fotokemija; Wittigova reakcija
• Keywords (english): heterocyclic compounds; furan; photochemistry; Wittig reaction
• Language: croatian
• URN:NBN: urn:nbn:hr:149:366097
• Study programme: Title: Applied Chemistry - Undergraduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry; Course: Applied organic chemistry; Study programme type: university; Study level: undergraduate; Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije)
• Type of resource: Text
• File origin: Born digital
• Access conditions: Open access
• Created on: 2021-03-12 10:03:20