Funkcionalizacija benzobiciklo[3.2.1]oktadienskog skeleta reakcijom fotokatalitičke oksigenacije u lužnatom mediju

undergraduate thesis

• Title (english): Functionalization of the benzobicyclo[3.2.1]diene skeleton via photocatalytic oxygenation in alkaline medium
• Author: Mia Dubravić
• Mentor: Dragana Vuk (mentor)
• Committee member: Dragana Vuk (predsjednik povjerenstva)
• Committee member: Irena Škorić (član povjerenstva)
• Committee member: Danijela Ašperger (član povjerenstva)
• Granter: University of Zagreb; Faculty of Chemical Engineering and Technology; Zagreb
• Defense date and country: 2016-09-01, Croatia
• Scientific / art field, discipline and subdiscipline: NATURAL SCIENCES; Chemistry; Organic Chemistry

Abstract

U cilju funkcionalizacije benzobiciklo[3.2.1]oktadienskog skeleta, provedene su reakcije fotokatalitičke oksigenacije. Reakcije oksigenacije provedene su na tiofenskom derivatu 1 i bicikličkom spoju 2, pri različitim eksperimentalnim uvjetima u smjesi aceton-voda, uz kationski/anionski Mn(III)-porfirin kao katalizator, te propuhivanjem kisikom/zrakom. Po uzoru na prethodna istraživanja reakcije su provedene u lužnatom mediju, pri čemu su dobiveni potpuno različiti rezultati u odnosu na reakcije u neutralnom mediju.

Abstract (english)

In order to functionalize benzobicyclo[3.2.1]octadiene skeleton, reactions of photocatalytic oxygenation were carried out. Reactions of photocatalytic oxygention were carried out on thiophene derivative 1 and bicyclic compound 2 in oxygen/air saturated acetone-water mixture, using anionic/cationic Mn(III) porphyrin as photocatalyst. In addition to earlier studies, the reactions were performed in alkaline medium, which gave completely different results compared to the reactions in the neutral medium.

• Keywords: benzobiciklo[3.2.1]oktadienski skelet; fotokatalitička oksigenacija; Mn(III)-porfirin
• Keywords (english): benzobicyclo[3.2.1]octadiene skeleton; photocatalytic oxygenation; Mn(III) porphyrin
• Language: croatian
• URN:NBN: urn:nbn:hr:149:594152
• Study programme: Title: Chemical Engineering - Undergraduate study; Study programme type: university; Study level: undergraduate; Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
• Type of resource: Text
• File origin: Born digital
• Access conditions: Open access
• Created on: 2018-01-30 10:51:23