Ekstrakcija eteričnog ulja i koncentrata iz smilja

master's thesis

• Title (english): Extraction of essential oil and absolute from immortelle
• Author: Dominik Kosir
• Mentor: Aleksandra Sander (mentor)
• Committee member: Aleksandra Sander (predsjednik povjerenstva)
• Committee member: Jasna Prlić Kardum (član povjerenstva)
• Committee member: Tatjana Gazivoda Kraljević (član povjerenstva)
• Granter: University of Zagreb; Faculty of Chemical Engineering and Technology; Zagreb
• Defense date and country: 2017-09-27, Croatia
• Scientific / art field, discipline and subdiscipline: TECHNICAL SCIENCES; Chemical Engineering; Mechanical, Thermal and Separation Processes

Abstract

Prirodni proizvodi sve više dobivaju na važnosti zahvaljujući porastu značaja „zelene kemije“, a zbog svoje raznovrsnosti predstavljaju ogroman potencijal za razvoj novih i naprednijih proizvoda. Posebna pažnja okrenuta je prema eteričnim uljima dobivenima iz raznih biljaka. Zbog raznovrsnosti spojeva koji se u njima nalaze, te dokazanim ljekovitim učincima, eterična ulja su od velike važnosti za industrije okusa i mirisa, te farmaceutsku, prehrambenu i kozmetičku industriju. U ovom radu ispitivane su različite metode i uvjeti ekstrakcije na izdvajanje eteričnog ulja i koncentrata iz smilja s područja Zapadne Hercegovine. Također je izvršena karakterizacija dobivenog ulja. Korištene metode su hidrodestilacija, vakuum destilacija, soxhlet ekstrakcija, te maceracija. Iz dobivenih rezultata utvrđeno je da je hidrodestilacija učinkovitija metoda za dobivanje eteričnog ulja u usporedbi s vakuum destilacijom, te da je soxhlet ekstrakcija učinkovitija od maceracije za dobivanje koncentrata. Također je ustanovljeno da maseno iskorištenje i sastav uvelike ovise o mjesecu berbe, te o količini proteklog vremena između branja i ekstrakcije ulja. Karakterizacijom dobivenog ulja utvrđeno je da se ono sastoji prvenstveno od seskviterpena, pretežno β-Himakalena, β-Selinena, α-Selinena i kariofilena, te estera i alkohola, ponegdje uz manji udio monoterpena. Udio neril acetata, kao jednog od pokazatelja kvalitete smilja opada sa starosti ubranog smilja.

Abstract (english)

Natural products are becoming more important because of the ever increasing interest in „green chemistry“. Because of their diversity they represent a huge potential for development of new and advanced products. Special attention has been given to essential oils extracted from different plants. Thanks to the diversity of the compounds found in those oils, and proven health benefits, essential oils are of great importance to various types of industries, pharmaceutical and cosmetic industry in particular. In this paper, different methods of extraction have been examined in order to determine the yield of essential oil and absolute from Helichrysum italicum from West Herzegovina under different conditions. Characterization of essential oil and absolute has also been performed. Methods that were used are hydrodistillation, vacuum distillation, soxhlet extraction, and leaching. It has been determined from the results that hydrodistillation is the more efficient method for obtaining essential oil compared to vacuum distillation, and that soxhlet extraction is more efficient than leaching for extracting absolute. It has also been determined that mass yield and the composition of essential oil and absolute depend on the month in which the plant was harvested, as well as the amount of time passed between harvesting the plant and extracting the oil or absolute from it. By characterizing the oil and absolute it has been determined that it consists mostly of sesquiterpenes, primarily β-Himachalene, β-Selinene, α-Selinene and Caryophyllene, with some esthers, alcohols and monoterpenes in certain samples. The amount of neryl acetate, as one of the indicators of the quality of oil, drops with time passed between the harvest and extraction.

• Keywords: Immortelle; Helichrysum italicum; ekstrakcija; eterično ulje; destilacija
• Keywords (english): Immortelle; Helichrysum italicum; extraction; essential oil; distillation
• Language: croatian
• URN:NBN: urn:nbn:hr:149:178716
• Study programme: Title: Chemical Engineering - Graduate study; Study programme type: university; Study level: graduate; Academic / professional title: magistar/magistra inženjer/inženjerka kemijskog inženjerstva (magistar/magistra inženjer/inženjerka kemijskog inženjerstva)
• Type of resource: Text
• File origin: Born digital
• Access conditions: Open access
• Created on: 2020-04-27 12:40:56